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Dissolve instant coffee in warm water. Set aside to cool down.
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For the coffee foam: in a bowl, add white sugar, coffee granules, and hot water. Beat using an electric hand mixer until stiff. You can also use a wire whisk but it may take longer time. Set aside.
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In a blender, add cooled coffee, milk, heavy cream, cocoa powder, chopped chocolate, and ice cubes. Blend until desired consistency is achieved.
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Before serving, you can beat the coffee foam again to make it more stiff.
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Place the frappe in a glass and then put the coffee foam on top. You may add more chocolate syrup and chopped chocolate on top.